Effect of Fiber Type on the Thermomechanical Performance of High-Density Polyethylene (HDPE) Composites with Continuous Reinforcement

Published: 2025

Author(s):

Quintana, Jose
Tomlinson, Scott
Lopez-Anido, Roberto

Publication Name: Journal of Composites Science

Publication URL: https://doi.org/10.3390/jcs9080450

Research Area:

Material Development & Characterization

Keywords:

extreme environments, Fiber reinforced composites, HDPE, material characterization, thermomechanical properties, UHMWPE, viscoelastic properties

Abstract:

The thermal, thermomechanical, and viscoelastic properties of continuous unidirectional (UD) glass fiber/high-density polyethylene (GF/HDPE) and ultra-high-molecular-weight polyethylene/high-density polyethylene (UHMWPE/HDPE) tapes are characterized in this paper in order to support their use in extreme environments. Unlike prior studies that focus on short-fiber composites or limited thermal conditions, this work examines continuous fiber architectures under five operational environments derived from Army Regulation 70-38, reflecting realistic defense-relevant extremes. Differential scanning calorimetry (DSC) was used to identify melting transitions for GF/HDPE and UHMWPE/HDPE, which guided the selection of test conditions for thermomechanical analysis (TMA) and dynamic mechanical analysis (DMA). TMA revealed anisotropic thermal expansion consistent with fiber orientation, while DMA, via strain sweep, temperature ramp, frequency sweep, and stress relaxation, quantified their temperature- and time-dependent viscoelastic behavior. The frequency-dependent storage modulus highlighted multiple resonant modes, and stress relaxation data were fitted with high accuracy (R² > 0.99) to viscoelastic models, yielding model parameters that can be used for predictive simulations of time-dependent material behavior. A comparative analysis between the two material systems showed that UHMWPE/HDPE offers enhanced unidirectional stiffness and better low-temperature performance. At the same time, GF/HDPE exhibits lower thermal expansion, better transverse stiffness, and greater stability at elevated temperatures. These differences highlight the impact of fiber type on thermal and mechanical responses, informing material selection for applications that require directional load-bearing or dimensional control under thermal cycling. By integrating thermal and viscoelastic characterization across realistic operational profiles, this study provides a foundational dataset for the application of continuous fiber thermoplastic tapes in structural components exposed to harsh thermal and mechanical conditions.